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Lithium cells are charged in two stages. In constant current, the charger pushes a fixed current and the cell voltage climbs steadily. Once the cell reaches its maximum voltage — typically 4.2 V for lithium cobalt chemistries, 3.65 V for LiFePO4 — the charger switches to constant voltage, holding that level while the current tapers away.
The constant-current phase delivers roughly 70–80% of the capacity and is comparatively quick. The constant-voltage tail delivers the remainder and takes a disproportionate share of the time, because current falls exponentially as the cell approaches full charge. Charging is normally considered complete when the current drops to about 3–5% of the initial rate.
This is why manufacturers quote 10–80% charging times, and why stopping at 80% on a public charger is usually the better use of time.
Exceeding the maximum cell voltage drives lithium plating on the anode: metallic lithium deposits instead of intercalating into the structure. That permanently removes capacity, and the resulting dendrites can eventually pierce the separator and cause an internal short. The voltage limit is a safety boundary, not a performance guideline, and the same applies to charging a cold cell, where the same plating occurs even at normal voltage.
Lead-acid uses bulk, absorption and float stages. The float stage holds a reduced voltage indefinitely to offset self-discharge, which is appropriate for that chemistry. Lithium cells must not be float-charged — holding them at full voltage accelerates calendar ageing, which is why a lithium charger terminates rather than floating.
Temperature compensation is also a lead-acid concern: charge voltage must be reduced as temperature rises, typically a few millivolts per cell per degree, or the battery will be overcharged in warm conditions and undercharged in cold.
Constant current until the cell reaches its voltage limit, then constant voltage while the current tapers. The current phase delivers most of the capacity; the voltage phase completes the charge slowly.
Because in the constant-voltage phase the current falls exponentially as the cell fills. Charging typically terminates when current drops to about 3–5% of the initial rate.
Lithium plates as metal on the anode instead of intercalating, permanently removing capacity and forming dendrites that can eventually short the cell internally. The voltage limit is a safety boundary.
No. Holding a lithium cell at full voltage accelerates calendar ageing. Lithium chargers terminate when the current falls below threshold, unlike lead-acid chargers which float indefinitely.
Because low temperature promotes lithium plating even at normal charge voltage. Most battery management systems block or heavily limit charging below roughly 0 °C for this reason.
Yes. Charge voltage must fall as temperature rises, typically a few millivolts per cell per degree, otherwise the battery is overcharged when warm and undercharged when cold.